International Journal of Environmental Research

International Journal of Environmental Research

Aqueous Phase Thiosulfate Removal Using Photo catalysis

Authors
Civil Engineering Department, King Fahd University of Petroleum and Minerals, Dhahran, Kingdom of Saudi Arabia 31261
Abstract
Removal of thiosulfate (S2O32-, 200 mg/L) from simulated wastewater samples was investigated under varying co-pollutants and pH conditions employing the titanium dioxide (TiO2) mediated photocatalysis. For thiosulfate only studies higher substrate removal was noted at lower pH with a specific trend of pH 4 > pH 7 > pH 10. Furthermore, near complete thiosulfate removal was also achieved at pH 4. A similar thiosulfate removal trend was also noted for the binary thiosulfate & p-cresol and thiosulfate & thiocyanate systems at pH 4, indicating high photocatalysis process efficiency. However, thiosulfate removal from the mixed systems at pH greater than 4 was slower as compared to the respective thiosulfate only systems. Nevertheless for the binary thiosulfate & thiocyanate system, significant thiosulfate removal was noted even at pH 12 when the thiosulfate concentration was reduced to 40 mg/L.
Keywords